Lithium Fluoride Crystal

Lithium Fluoride (LiF) Crystal
Product Lithium Fluoride (LiF) Crystal
Part Number SB19

About Lithium Fluoride (LiF) Crystal

Lithium Fluoride (LiF) Crystal is an optical material with outstanding transmittance in VUV region. It is widely used in windows, prisms and lenses for 0.105 µm-6 µm visible light and infrared light.

Optical Properties

Transmission Range 105 nm to 6 μm
Refractive Index 1.3733 at 2.5 μm; 1.6240 at 121 nm
Reflection Loss 4.4% at 4 μm

Advantages of LiF:

LiF single crystal is sensitive to thermal shock and would be attacked by atmospheric moisture at 400°C. When working at a high temperature of 600°C, the LiF crystal softens and is slightly plastic, so it can be bent into radius plates. In addition, radiation produces color centers. Hence, users should take measures to protect LiF crystals from moisture and high energy radiation damages.

NCE provides LiF crystals grown using Czochralski technology. In addition, we can also provide other types of window crystals like YAG, BaF2, and MgF2 crystals, etc. Please contact us for more details. Get a Quote Now! For other optical materials, please check our Optical Materials category page.

Other Trade Name: single crystal LiF

Typical Applications of LiF:

Lithium Fluoride Crystal is used as windows, lenses for the 105 nm to 6 μm light. And it can also be used as the optical element in X-ray diffraction devices.

Typical Specification – Lithium Fluoride (LiF) Crystal

Orientation: <100> or others on request
Wavefront Distortion: λ/4 per inch @ 632.8 nm
Dimension Tolerances: ±0.1 mm
Surface Quality: 20/10 Scratch
Parallelism: < 20″
Perpendicularity: < 10′
Clear Aperture: > 90%
Surface Flatness: < λ/8 @ 632.8 nm
Chamfer: < 0.25 mm @ 45 deg.
Size: Upon customer request

Order Information

Inquiries and orders should include the following information:

  1. Quantity
  2. Dimensions
  3. Crystal orientation
  4. Polishing or grind finish

Packing and Storage

Standard Packing: 100 pcs in clean sealed bags. Special package is available on request.

Typical Properties of LiF Crystal

Density 2.64 g/cm3
Melting Point 845°C
Molar Mass 25.9394
Lattice Parameters 4.0279 Å
Thermal Conductivity 4.01 W/(m·K)
Specific Heat 1562 (J·kg-1·K-1)
Thermal Expansion Coefficient 28.1 – 34.8 (10-6/K)
Knoop Hardness 102–103 kg/mm2
Mohs Hardness 3
Young’s Modulus 64.79 GPa
Shear Modulus 55.14 GPa
Bulk Modulus 62.03 GPa
Rupture Modulus 10.8 MPa
Elastic Coefficient C11 = 112 / C12 = 45.6 / C44 = 3.2 GPa
Crystal Type Cubic
Dielectric Constant 9.0 @ 25°C, f = 100…109 Hz
Solubility in Water 0.27 (g/100 cm3) @ 18°C
Apparent Elastic Limit/ MPa 11.2 @1620 psi
Cleavage (100)